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OLED材料發展現況

 

電子傳輸材料(electron transport materials)

   
   
   
   
   
   
   
   
   
   
   
   
   
   
   
   
 


I. Brief Introduction

Color changes of thermochromic pigments are induced by a temperature change. The pigments are composed of microcapsules that change colors reversibly. When temperature rises to a specific temperature the color changes. The color starts fading back to the original color as the pigment is cooled down.

low temperature
heated
high temperature

color appears
cooled
Colorless


II. Product Feature
Nine Standard Colors


Standard colors are violet, blue, light blue, green, yellow, orange, red and black.

Shade
Color Base
Item #
Pantone #
Note
 
Yellow
TCP59-temp
108C
 
Orange
TCP63-temp
021C
 
Magenta
TCP70-temp
Rubine Red C
 
Red
TCP69-temp
186C
 
Green
TCP52-temp
335C
 
Sky Blue
TCP49-temp
313C
 
Blue
TCP45-temp
301U
 
Violet
TCP40-temp
2728C
 
Black
TCP10-temp
Black 5C2X
Primary Color
YT/MT/ST
Temp from
-15oC to 65oC
(standard is 31oC)

Example: TCP59-31 (Yellow thermochromic pigment with color change at 31oC )

A. Temperature of color changes
When the temperature is increased to a specific temperature, the color starts fading to colorless. The specific temperature of the color changes can be assigned at temperatures between 15oC to 65oC. The sensitivity of color changes is within 2oC to 10oC. The temperature of the color change set under 33oC has a fine sensitivity and those over 33oC are coarser.

 
 
 
-15oC 20oC 31oC 43oC 70oC


Example 1. TCP45-20 indicates the blue thermochromic pigment changes its color when it is heated to 20 o C and become completely colorless at 22 o C. Conversely, the color starts to reveal when the temperature is decreased. It is recommended to use this temperature
for cold drinks.
Example 2. TCP63-31 indicates the orange thermochromic pigment changes its color when it is heated to 31 o C and become completely colorless at 35 o C. Conversely, the color starts to reveal when the temperature is decreased. This product is most suitable for products that change colors at body temperature.
Example 3. TCP69-43 indicates the red thermochromic pigment changes its color when it is heated to 43 o C and becomes completely colorless around at 47 o C. Conversely, the color starts to reveal when the temperature is decreased. It could be used as a caution for hot drinks.

 

III. Reference Colors for Application

A. By using three primary colors, you can adjust any color as you expect. You may mix different colors of thermochromic pigments with the same temperature to create more colors.

+
mixture
heat

The following are some samples for your reference.


They can also be mixed with regular pigments so that the color can be changed from one to another. At lower temperature, the color reveals matched shade. When the temperature is increased, the thermochromic pigments start fading to colorless. It only shows color of the regular pigments.


Regular
+


Thermochromic
Pigment
mixture

The following are some samples as references.

B. By mixing the thermochromic pigments with different temperature ranges, the color can be varied for more than two colors.

Temperature ranges for 3-color variation
<0oC
0o~25oC >25oC <10oC 10oC~25oC >25oC

 

<30oC 30oC~45oC >45oC <33oC 33oC~55oC <55oC


Features:
A. Thermochromic pigments:

Composed of microcapsules
Distribution of particle size is between 1~6
Heat resistance is up to 280oC
Moisture content is about 0.3%
The shelf life of thermochromic pigments is approximately 2 years.


Application and Formulation Suggestions
A. Thermochromic pigments can be applied in coloring of plastics, paints, inks, dyes and dyed fabrics.

B. Dosage of application.

Materials Ink, Paint
Solvent type
Ink, Paint
Water Type
Plastic
Injection/Extrusion
Pigment %
Pigment %
Pigment %
Thermochromic pigment
5.0% ~ 30%
3.0% ~ 15%
0.5% ~ 3%



C. The products must be stored at room temperature, in a dry area and not exposed to sun.
D. For printing inks, it is recommended to adjust the pH value of resin between 4-7.
E. Toluene will affect the properties of the microcapsules. Avoid using as a solvent. If using a solvent mixture, try to minimize the toluene content.

The information herein is believed to be reliable and is to assist customers in determining whether our products are suitable for their applications. However, no warranty, express or implied, is made as to its accuracy or completeness and none is made as to fitness of this material for any purpose. Our products are intended for sale to industrial and commercial customers. We request that customers inspect and test our products before use and satisfy themselves as to contents and suitability. Nothing herein shall constitute any other warranty, express or implied, including any warranty of merchantability or fitness, nor of protection from any law or patent to be inferred. All patent rights are reserved. The exclusive remedy for all proven claims is replacement of our materials and in no event shall we be liable for special, incidental or consequential damages. We shall not be liable for damages to person or property resulting from its use. Consult the Material Safety Data Sheet for additional information.

 

 

 

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